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Shakhtar Donetsk sealed second place in Group F by handing Man City their first defeat of the 2017/18 season.
Cristiano Ronaldo became the first player to score in every Champions League group stage match as Real Madrid beat Borussia Dortmund 3-2.
Ten-man Porto advanced out of Group G with a 5-2 defeat of a disappointing Monaco side, who also went down a man at the Estadio do Dragao.
Philippe Coutinho and Liverpool scored early and never looked back, putting seven past Spartak Moscow on their way to winning Group E.
Fernando Llorente and Georges-Kevin Nkoudou scored their first goals for Tottenham goal as Spurs strolled into the Champions League round of 16.
Having already sealed top spot in Group H, Tottenham finished off the group stage with a comfortable win over Apoel.