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Gregoire Defrel moved to top of the Serie A goal standings with a brace in Sampdoria's five-goal demolition of newly-promoted Frosinone.
Napoli exorcised some of the ghosts of last season by beating Fiorentina 1-0 in Serie A action on Saturday.
Napoli missed chance after chance against Fiorentina, but a late goal from Lorenzo Insigne secured three points for Carlo Ancelotti's side.
Massimiliano Allegri tips Cristiano Ronaldo to open his Juventus account against Sassuolo.
On loan from Inter Milan, Federico Dimarco scored a wonder goal for Parma in the second half on route to a 1-0 win.
Inter Milan's tough start to the season continued as they were beaten 1-0 by Parma thanks to a late goal from Federico Dimarco.